The Last of Mercenary Tao Dragon Ball: Doragon bôru : Season 1 Episode 64

Having climbed Karin Tower, Tao Pai-pai tries to get the Super Sacred Water by threatening Karin-sama. However, Karin-sama successfully tricks Tao Pai-pai, and sends him back to the surface! After descending back to the holy land, Tao Pai-pai unleashes a violent attack, but Goku is unharmed!! Tao Pai-pai turns pale and uses a bomb, but Goku kicks it back and Tao Pai-pai ends up blowing himself away. After gathering the four Dragon Balls, Goku flies off to the Red Ribbon Army Headquarters to gather the remaining ones!!